Issue 45, 2023

Reversible single-crystal to single-crystal transformation between triangular single-molecule toroics

Abstract

We report a method for synthesizing single-molecule magnets through a single-crystal to single-crystal transformation. This process yields two single-molecule magnets with similar triangular Dy3 cores but distinct solvents and space groups achieved via solvent exchange. Magnetic properties reveal that both Dy3 molecules exhibit similar toroidal moments but manifest diverse multiple magnetization dynamic behaviors owing to the spin–lattice coupling influence from different solvent molecules.

Graphical abstract: Reversible single-crystal to single-crystal transformation between triangular single-molecule toroics

Supplementary files

Article information

Article type
Communication
Submitted
28 Sep 2023
Accepted
20 Oct 2023
First published
03 Nov 2023

Dalton Trans., 2023,52, 16596-16600

Reversible single-crystal to single-crystal transformation between triangular single-molecule toroics

L. Feng, Y. Yang, Y. Wang, Y. Zhao, Z. Liu, J. Cong, Y. Zhang and P. Cheng, Dalton Trans., 2023, 52, 16596 DOI: 10.1039/D3DT03191H

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