Ba3(BS3)(PS4): the first alkaline-earth metal thioborate–thiophosphate with strong optical anisotropy originating from planar [BS3] units

Jiazheng Zhou; Linan Wang; Hongshan Wang; Ling Luo; Junjie Li; Feng Yu

doi:10.1039/D3DT02807K

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Ba₃(BS₃)(PS₄): the first alkaline-earth metal thioborate–thiophosphate with strong optical anisotropy originating from planar [BS₃] units†

Jiazheng Zhou,‡^ab Linan Wang,‡^b Hongshan Wang,^b Ling Luo,^b Junjie Li

*^b and Feng Yu

*^a

Author affiliations

* Corresponding authors

^a Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, School of Chemistry and Chemical Engineering, Shihezi University, Shihezi 832003, China
E-mail: yufeng05@mail.ipc

^b Research Center for Crystal Materials; CAS Key Laboratory of Functional Materials and Devices for Special Environments, Xinjiang Technical Institute of Physics & Chemistry, CAS; Xinjiang Key Laboratory of Electronic Information Materials & Devices, Urumqi 830011, China
E-mail: lijunjie@ms.xjb.ac.cn

Abstract

The first alkaline-earth metal thioborate–thiophosphate Ba₃(BS₃)(PS₄) was designed from Ba₃(BO₃)(PO₄) by S–O substitution and fabricated experimentally. The [BS₃] pseudo-layers formed in the structure contribute to the strong optical anisotropy and a large birefringence of ∼0.11 at 1064 nm. The results enrich the structural and chemical diversity of chalcogenides.

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Article information

DOI: https://doi.org/10.1039/D3DT02807K
Article type: Communication
Submitted: 29 Aug 2023
Accepted: 23 Oct 2023
First published: 26 Oct 2023

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Dalton Trans., 2023,52, 16113-16117

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Ba₃(BS₃)(PS₄): the first alkaline-earth metal thioborate–thiophosphate with strong optical anisotropy originating from planar [BS₃] units

J. Zhou, L. Wang, H. Wang, L. Luo, J. Li and F. Yu, Dalton Trans., 2023, 52, 16113 DOI: 10.1039/D3DT02807K

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