A phthalocyanine-based porous organic polymer for a lithium-ion battery anode

Abstract

Porous organic polymers (POPs) are a novel class of polymeric materials with high flexibility and designability for building structures. Herein, a phthalocyanine-based porous organic polymer (PcPOP) was constructed in situ on copper foil from H₂Pc(ethynyl)₄ [Pc(ethynyl)₄ = 2(3),9(10),16(17),23(24)-tetra(ethynyl)phthalocyanine] by the coupling reaction. Benefiting from the uniformly distributed electron-rich nitrogen atoms in the Pc structure and the sp-hybridized carbons in the acetylenic linkage, Li intercalation in the porous organic polymer would be improved and stabilized. As a result, PcPOP showed remarkable electrochemical performance in lithium-ion batteries as the anode, including high specific capacity (a charge capacity of 1172 mA h g⁻¹ at a current density of 150 mA g⁻¹) and long cycling stability (a reversible capacity of 960.1 mA h g⁻¹ can be achieved even after 600 cycles at a current density of 1500 mA g⁻¹). The result indicates that the intrinsic doping of electron-rich sites of the building molecules is beneficial for the electrochemical performance of the porous organic polymer.