Issue 43, 2023
From the journal:

Dalton Transactions

Synthesis of fluorinated aminium cations coupled with carborane anions for use as strong one-electron oxidants†

Jillian J. Davidson,a   S. Olivia Gunther,a   Derek W. Leonga  and  Oleg V. Ozerov ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Texas A&M University, College Station, TX 77842, USA
E-mail: ozerov@chem.tamu.edu

Abstract

Synthesis of a series of hydrocarbon-soluble triarylamines bearing F, CF3, and Br substituents showing quasi-reversible redox events in the 0.59–1.32 V range is reported. Chemical oxidation of the amines was carried out with 0.5PhI(OAc)2/Me3SiX/Na[RCB11Cl11] (X = Cl or OTf, R = H or Me), and a few aminium salts were isolated as pure solids.

Graphical abstract: Synthesis of fluorinated aminium cations coupled with carborane anions for use as strong one-electron oxidants

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Article information

DOI
https://doi.org/10.1039/D3DT02127K
Article type
Paper
Submitted
06 Jul 2023
Accepted
10 Oct 2023
First published
12 Oct 2023

Dalton Trans., 2023,52, 16027-16031

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Synthesis of fluorinated aminium cations coupled with carborane anions for use as strong one-electron oxidants

J. J. Davidson, S. O. Gunther, D. W. Leong and O. V. Ozerov, Dalton Trans., 2023, 52, 16027 DOI: 10.1039/D3DT02127K

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