Issue 31, 2023

Interaction of germanium analogue of organic isonitrile with Cu(i) imide in side-on mode

Abstract

[NHC → GeN(Ar)Cu2NAr]2, the formal adduct of germanium analogue of organic isonitrile [GeNAr] with Cu(I) imide [(Cu2NAr)2] (Ar = 2,6-iPr2C6H3) was prepared from the N-heterocyclic carbene (NHC) stabilized acyclic germylene Ge[N(H)Ar]2 by reacting with two equivalents of nBuLi and CuCl(PPh3)3. As elucidated by X-ray crystal structural characterization, the two separated [GeNAr] moieties interacted with [(Cu2NAr)2] core in the side-on mode.

Graphical abstract: Interaction of germanium analogue of organic isonitrile with Cu(i) imide in side-on mode

Supplementary files

Article information

Article type
Communication
Submitted
04 Jul 2023
Accepted
19 Jul 2023
First published
20 Jul 2023
This article is Open Access
Creative Commons BY license

Dalton Trans., 2023,52, 10672-10676

Interaction of germanium analogue of organic isonitrile with Cu(I) imide in side-on mode

S. Huo, Y. Li, P. Ji, D. Zhang, Y. Yang and H. W. Roesky, Dalton Trans., 2023, 52, 10672 DOI: 10.1039/D3DT02094K

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