Ligand leaching enabling improved electrocatalytic oxygen evolution performance

Abstract

Design and fabrication of cost-effective (pre-)catalysts are important for water splitting and metal–air batteries. In this direction, various metal–organic frameworks (MOFs) have been investigated as pre-catalysts for oxygen evolution. However, the activation process and the complex reconstruction behaviour of these MOFs are not well understood. Herein, square-like MOF nanosheets in which carbon nanotubes were embedded were prepared by introducing an amine ligand to coordinate with Ni ions and then reacting with [Fe(CN)₆]³⁻. The formed MOF nanosheets containing nickel and iron species were then activated by NaBH₄, inducing the leaching of ligands and the formation of tiny active species in situ loaded on carbon nanotubes. The prepared catalyst shows superior oxygen evolution performance with an ultralow overpotential of 231 mV for 10 mA cm⁻², a fast reaction kinetics with a small Tafel slope of 52.3 mV dec⁻¹, and outstanding catalysis stability. The excellent electrocatalytic performance for oxygen evolution can be attributed to the structural advantage of in situ derived small sized active species and one-dimensional conductive networks. This work provides a new thought for the enhancement of the electrocatalytic performance of MOF materials.