Improving upconversion luminescence intensity of BiTa7O19:Er3+/Yb3+ by polyvalent Sb co-doping

Abstract

BiTa₇O₁₉:Er³⁺/Yb³⁺/Sb phosphors were successfully synthesized by high temperature solid sintering. X-ray diffraction (XRD), fluorescence spectrometry and X-ray photoelectron spectroscopy (XPS), were used to analyze the phase structure, upconversion luminescence (UCL) features and Sb valence state, respectively. The results suggest that polyvalent Sb with Sb³⁺ and Sb⁵⁺ can replace the Ta⁵⁺ sites in a BiTa₇O₁₉ host to form a pure phase. Compared with BiTa₇O₁₉:0.1Er³⁺/0.4Yb³⁺, polyvalent Sb doping further improves UCL intensity by 1.2 times under 980 nm laser stimulation with a powder density of 44.59 W cm⁻². This is due to the adjustment of the local lattice structure of BiTa₇O₁₉ by the polyvalent Sb. The maximum absolute sensitivity (S_A) and relative sensitivity (S_R) can be estimated from the UCL variable-temperature spectra as 0.0098 K⁻¹ at 356 K and 0.0078 K⁻¹ at 303 K using the luminescence intensity ratio (LIR) approach. The outcomes show that host local lattice adjustment using polyvalent elements is an effective way to improve luminescence intensity, and it is possible to use BiTa₇O₁₉:Er³⁺/Yb³⁺/Sb as a temperature sensor.