Issue 26, 2023

Harnessing the hydrogen evolution reaction (HER) through the electrical mobility of an embossed Ag(i)-molecular cage and a Cu(ii)-coordination polymer

Abstract

A structurally characterized porous Ag(I)-molecular cage AgMOC and a Cu(II)-coordination polymer CuCP with a pre-synthesized ligand 1,3-bis(((E)-2-methoxybenzylidene)amino)propan-2-ol and its parental amine with thiocyanate are reported to harness electrical mobility-driven hydrogen evolution activity. Porosity-induced electrically conductive AgMOC emerges as a better electrocatalyst with a Tafel slope of 104 mV per decade over Cu(II)-polymer's slope of 128 mV per decade. The electrochemical stability and durability of the designed electrocatalysts in harnessing the HER activity are also examined under experimental conditions.

Graphical abstract: Harnessing the hydrogen evolution reaction (HER) through the electrical mobility of an embossed Ag(i)-molecular cage and a Cu(ii)-coordination polymer

Supplementary files

Article information

Article type
Communication
Submitted
07 Apr 2023
Accepted
06 Jun 2023
First published
09 Jun 2023

Dalton Trans., 2023,52, 8850-8856

Harnessing the hydrogen evolution reaction (HER) through the electrical mobility of an embossed Ag(I)-molecular cage and a Cu(II)-coordination polymer

A. Debnath, S. Diyali, M. Das, S. J. Panda, D. Mondal, D. Dhak, C. S. Purohit, P. P. Ray and B. Biswas, Dalton Trans., 2023, 52, 8850 DOI: 10.1039/D3DT01073B

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