Issue 19, 2023

Dimeric and 1D polymeric low-chlorinated C60 fullerenes, (C60Cl5)2 and (C60Cl4)

Abstract

Low-chlorinated fullerenes, dimeric (C60Cl5)2 and one-dimensional, polymeric (C60Cl4), were obtained by high-temperature (270 °C) chlorination of C60 with a SbCl5/SbCl3 mixture, as revealed by X-ray crystallography. The compounds were characterized by IR and Raman spectroscopy and theoretical calculations. This is the first observation of a fullerene polymer with single C−C bonding and neutral building blocks.

Graphical abstract: Dimeric and 1D polymeric low-chlorinated C60 fullerenes, (C60Cl5)2 and (C60Cl4)∞

Supplementary files

Article information

Article type
Communication
Submitted
23 Mar 2023
Accepted
21 Apr 2023
First published
28 Apr 2023

Dalton Trans., 2023,52, 6244-6247

Dimeric and 1D polymeric low-chlorinated C60 fullerenes, (C60Cl5)2 and (C60Cl4)

V. A. Brotsman, N. B. Tamm, I. N. Ioffe, A. A. Eliseev, A. A. Goryunkov, K. A. Lyssenko and S. I. Troyanov, Dalton Trans., 2023, 52, 6244 DOI: 10.1039/D3DT00887H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements