A {Cu6}-added polyoxometalate cluster–organic framework: synthesis, structure and application as a solid support for enzyme immobilization

Zhao-Min Su; Yongchun Wang; Zhikun Xu; Wenhui Shang; Zhiyu Jia; Guo-Yu Yang

doi:10.1039/D3DT00822C

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A {Cu₆}-added polyoxometalate cluster–organic framework: synthesis, structure and application as a solid support for enzyme immobilization†

Zhao-Min Su,‡^a Yongchun Wang,‡^a Zhikun Xu,^b Wenhui Shang,^a Zhiyu Jia

*^a and Guo-Yu Yang

*^a

Author affiliations

* Corresponding authors

^a MOE Key Laboratory of Cluster Science, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, P. R. China
E-mail: jzy@bit.edu.cn, ygy@bit.edu.cn

^b College of Veterinary Medicine, Henan University of Animal Husbandry and Economy, Longzihu North road No 6, Zhengzhou, Henan, P. R. China

Abstract

A new two-dimensional {Cu6}-added polyoxometalate cluster–organic framework (Cu-POMCOF) was prepared by a hydrothermal method from lacunary polyoxoanions and was applied as a solid support for immobilizing MP-11 and Cyt c. The biocomposite complex exhibits higher stability and catalytic activity than the original free enzyme.

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Article information

DOI: https://doi.org/10.1039/D3DT00822C
Article type: Communication
Submitted: 18 Mar 2023
Accepted: 03 May 2023
First published: 04 May 2023

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Dalton Trans., 2023,52, 6624-6628

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A {Cu₆}-added polyoxometalate cluster–organic framework: synthesis, structure and application as a solid support for enzyme immobilization

Z. Su, Y. Wang, Z. Xu, W. Shang, Z. Jia and G. Yang, Dalton Trans., 2023, 52, 6624 DOI: 10.1039/D3DT00822C

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