Issue 5, 2023

A robust thorium–organic framework as a bifunctional platform for iodine adsorption and Cr(vi) sensitization

Abstract

Simple synthetic modulation based on thorium nitrate and tris((4-carboxyl)phenylduryl)amine (H3TCBPA) gives rise to a new thorium-based metal–organic framework, Th-TCBPA, which features excellent hydrolytic and thermal stabilities. Incorporating electron-rich TCBPA3− linkers not only endows Th-TCBPA with high adsorption capacity toward radioiodine vapor, but also makes it a luminescence sensor for the highly sensitive and selective detection of Cr(VI) anions.

Graphical abstract: A robust thorium–organic framework as a bifunctional platform for iodine adsorption and Cr(vi) sensitization

Supplementary files

Article information

Article type
Communication
Submitted
11 Nov 2022
Accepted
05 Jan 2023
First published
06 Jan 2023

Dalton Trans., 2023,52, 1177-1181

A robust thorium–organic framework as a bifunctional platform for iodine adsorption and Cr(VI) sensitization

Y. Fu, X. Wang, Y. Ju, Z. Zheng, J. Jian, Z. Li, C. Jin, J. Wang and J. Lin, Dalton Trans., 2023, 52, 1177 DOI: 10.1039/D2DT03623A

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