Issue 3, 2023

σ-Hole triel bonds in aluminium derivatives

Abstract

This communication reports the synthesis and X-ray characterization of a new mononuclear aluminium compound exhibiting an intramolecular σ-hole triel bonding interaction. It is compared with a dinuclear aluminium compound, previously reported by us, where the aluminium atoms participate in two concurrent σ-hole triel bonding interactions. To our knowledge, such behaviour has not been previously described in the literature.

Graphical abstract: σ-Hole triel bonds in aluminium derivatives

Supplementary files

Article information

Article type
Communication
Submitted
06 Nov 2022
Accepted
18 Dec 2022
First published
21 Dec 2022

Dalton Trans., 2023,52, 551-555

σ-Hole triel bonds in aluminium derivatives

V. Tabernero, M. Teresa Muñoz, M. Palenzuela, R. M. Gomila, A. Frontera and M. E. G. Mosquera, Dalton Trans., 2023, 52, 551 DOI: 10.1039/D2DT03581B

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