Issue 22, 2023

Heterogenization of molecular catalysts within porous solids: the case of Ni-catalyzed ethylene oligomerization from zeolites to metal–organic frameworks

Abstract

The last decade has seen a tremendous expansion of the field of heterogenized molecular catalysis, especially with the growing interest in metal–organic frameworks and related porous hybrid solids. With successful achievements in the transfer from molecular homogeneous catalysis to heterogenized processes come the necessary discussions on methodologies used and a critical assessment on the advantages of heterogenizing molecular catalysis. Here we use the example of nickel-catalyzed ethylene oligomerization, a reaction of both fundamental and applied interest, to review heterogenization methodologies of well-defined molecular catalysts within porous solids while addressing the biases in the comparison between original molecular systems and heterogenized counterparts.

Graphical abstract: Heterogenization of molecular catalysts within porous solids: the case of Ni-catalyzed ethylene oligomerization from zeolites to metal–organic frameworks

Article information

Article type
Review Article
Submitted
30 May 2023
First published
30 Oct 2023
This article is Open Access
Creative Commons BY-NC license

Chem. Soc. Rev., 2023,52, 8059-8076

Heterogenization of molecular catalysts within porous solids: the case of Ni-catalyzed ethylene oligomerization from zeolites to metal–organic frameworks

R. Rajapaksha, P. Samanta, E. A. Quadrelli and J. Canivet, Chem. Soc. Rev., 2023, 52, 8059 DOI: 10.1039/D3CS00188A

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