Development of SrWO4:Ho3+/Yb3+ green phosphor for optical thermometry application

Abstract

In recent years, the growth of luminescent materials for optical thermometry applications has gained substantial attention due to their non-invasive and contactless nature. This research article presents the synthesis, characterization, and potential application of SrWO₄:Ho³⁺/Yb³⁺ phosphors as temperature-sensitive materials. The inspection of the structural properties is done by X-ray diffraction and Raman and FTIR spectroscopy. The X-ray diffraction signifies the single tetragonal phase of the materials without any impurity or secondary phase. Nine Raman active modes are detected in the Raman spectra of pure SrWO₄ and 10 Raman active bands are present in the doped samples. The morphology and elemental composition are visualised by field emission scanning electron microscopy (FESEM) and energy dispersive X-ray (EDX) spectroscopy. The spectral properties of these phosphors are evaluated by down-conversion and up-conversion photoluminescence, signifying their suitability for solid state lighting and optical thermometry in various temperature regimes. The phosphors can generate green and yellow light under blue and near-infrared radiation, respectively. The sensitivity of 3.19 × 10⁻³ K⁻¹ ensures the promising prospects of SrWO₄:Ho³⁺/Yb³⁺ phosphors for precise and reliable temperature sensing in diverse fields.