Issue 46, 2023

Photoinduced absorption spectroscopy (PIAS) study of water and chloride oxidation by a WO3 photoanode in acidic solution

Abstract

The mechanisms of water and chloride oxidation by a WO3 photoanode are probed by photoinduced absorption spectroscopy (PIAS) coupled with transient photocurrent (TC) measurements. Linear sweep voltammograms (LSVs) and incident photon to current efficiencies (IPCEs) are obtained, in the water oxidation electrolyte (1 M HClO4) and chloride oxidation electrolyte (3.5 M NaCl in 1 M HClO4). Other work shows that the faradaic efficiency of water oxidation to O2 in 1 M HClO4 is ca. 1.0, and that for chloride oxidation to Cl2 in 3.5 M NaCl plus 1 M HClO4 is ca. 0.62. The PIAS/TC data reveals a 0.4 order dependency of the rate of water oxidation on the steady state concentration of photogenerated surface holes, [hs+]ss, and an approximately first order dependency of the rate of chloride oxidation on [hs+]ss. Associated mechanisms and rate determining steps for water and chloride oxidation at the photoanode surface that account for these reaction orders are proposed.

Graphical abstract: Photoinduced absorption spectroscopy (PIAS) study of water and chloride oxidation by a WO3 photoanode in acidic solution

Supplementary files

Article information

Article type
Paper
Submitted
05 Jul 2023
Accepted
02 Nov 2023
First published
02 Nov 2023
This article is Open Access
Creative Commons BY license

Phys. Chem. Chem. Phys., 2023,25, 31825-31835

Photoinduced absorption spectroscopy (PIAS) study of water and chloride oxidation by a WO3 photoanode in acidic solution

J. Johnston, C. O’Rourke and A. Mills, Phys. Chem. Chem. Phys., 2023, 25, 31825 DOI: 10.1039/D3CP03167E

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