Issue 16, 2023

Luminescence–structure relationships in solids doped with Bi3+

Abstract

The luminescence properties of Bi3+ in 177 inorganic compounds are reviewed and rationalized based on two simple and easy-to-use models. These models are applicable to any kind of compound whose crystal structure is known. The calculation of the nephelauxetic function, he, involved in one of the models is described step-by-step for an easy implementation in a home-made calculator or machine-learning algorithm. Finally, a criterion based on the experimental value of the Stokes shift is introduced to help in fixing the origin of the Bi3+-related emission.

Graphical abstract: Luminescence–structure relationships in solids doped with Bi3+

Supplementary files

Article information

Article type
Perspective
Submitted
18 Jan 2023
Accepted
27 Mar 2023
First published
28 Mar 2023

Phys. Chem. Chem. Phys., 2023,25, 11027-11054

Luminescence–structure relationships in solids doped with Bi3+

P. Boutinaud, Phys. Chem. Chem. Phys., 2023, 25, 11027 DOI: 10.1039/D3CP00289F

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