High-performance Zn-ion batteries constructed by in situ conversion of surface-oxidized vanadium nitride into Zn3(OH)2V2O7·2H2O with oxygen defects

Abstract

Herein, surface-oxidized vanadium nitride (O-VN) is synthesized by a one-step hydrothermal method without multi-step reactions, and is applied as a cathode material for aqueous zinc ion batteries. After in situ electrochemical activation, it turns into Zn₃(OH)₂V₂O₇·2H₂O with copious oxygen vacancies/defects. The electrochemical phase transition and in situ defect induction can provide abundant active sites for the storage of Zn²⁺, thus increasing the energy storage performance of electrode materials. As expected, Zn₃(OH)₂V₂O₇·2H₂O with oxygen defects has good structural and morphological stability during cycling, and exhibits excellent specific capacity (510 mA h g⁻¹ at 0.1 A g⁻¹ and 199 mA h g⁻¹ at 10 A g⁻¹) and superior cycle stability (72.6% capacity retention after 3000 cycles at 20 A g⁻¹).