Issue 95, 2023

Expedient C–H allylation of sulfoxonium ylides: merging C–H and C–C/C–het bond activation

Abstract

Sulfoxonium ylide chelation-assisted C–H allylation of arenes has been accomplished utilizing strained vinyl carbo/heterocycles as the allyl surrogates via sequential C–H and C–C/het bond activation. Broad substrate scope, Co-catalysis, selectivity, and late-stage drug mutation are the important practical features.

Graphical abstract: Expedient C–H allylation of sulfoxonium ylides: merging C–H and C–C/C–het bond activation

Supplementary files

Article information

Article type
Communication
Submitted
11 Sep 2023
Accepted
30 Oct 2023
First published
31 Oct 2023

Chem. Commun., 2023,59, 14173-14176

Expedient C–H allylation of sulfoxonium ylides: merging C–H and C–C/C–het bond activation

S. Saha, H. Bhattacharyya, P. Karjee, B. Debnath, K. Verma and T. Punniyamurthy, Chem. Commun., 2023, 59, 14173 DOI: 10.1039/D3CC04507B

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