Influence of solvent on cyclic polynorbornene tacticity

Sung-Min Hyun; Arkadios Marathianos; Parker T. Boeck; Ion Ghiviriga; Daniel W. Lester; Brent S. Sumerlin; Adam S. Veige

doi:10.1039/D3CC04167K

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Influence of solvent on cyclic polynorbornene tacticity†

Sung-Min Hyun,

^a Arkadios Marathianos,

^b Parker T. Boeck,

^ac Ion Ghiviriga,^a Daniel W. Lester,^b Brent S. Sumerlin

^c and Adam S. Veige

*^a

Author affiliations

* Corresponding authors

^a University of Florida, Department of Chemistry, Center for Catalysis, P.O. Box 117200, Gainesville, FL, USA
E-mail: veige@chem.ufl.edu

^b Polymer Characterization Research Technology Platform, University of Warwick, Coventry CV4 7AL, UK

^c University of Florida, Department of Chemistry, George and Josephine Butler Polymer Research Laboratory, Center for Macromolecular Science and Engineering, Gainesville, FL 32611, USA

Abstract

Tacticity is critical to polymer properties. The influence of solvent on tacticity in the catalytic synthesis of cyclic polynorbornene (c-PNB) is reported. In toluene cis,syndiotactic c-PNB forms; in THF, cis,syn/iso c-PNB forms.

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Article information

DOI: https://doi.org/10.1039/D3CC04167K
Article type: Communication
Submitted: 28 Aug 2023
Accepted: 21 Oct 2023
First published: 31 Oct 2023

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Chem. Commun., 2023,59, 13993-13996

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Influence of solvent on cyclic polynorbornene tacticity

S. Hyun, A. Marathianos, P. T. Boeck, I. Ghiviriga, D. W. Lester, B. S. Sumerlin and A. S. Veige, Chem. Commun., 2023, 59, 13993 DOI: 10.1039/D3CC04167K

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Chemical Communications

Influence of solvent on cyclic polynorbornene tacticity†

Abstract

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Influence of solvent on cyclic polynorbornene tacticity

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