Issue 76, 2023
From the journal:

Chemical Communications

Synthesis of fused energetic compounds using structural modification from local carbonyl to hydroxylamine/hydrazone†

Caijin Lei,a   Chuan Xiao,b   Jie Tang,a   Hongwei Yang, ORCID logo *a   Qinghua Zhang ORCID logo c  and  Guangbin Cheng ORCID logo *a  

* Corresponding authors

a School of Chemical Engineering, Nanjing University of Science and Technology, Xiaolingwei 200, Nanjing, Jiangsu, China
E-mail: gcheng@mail.njust.edu.cn, hyang@mail.njust.edu.cn

b China Northern Industries Group Co., Ltd. (NORINCO GROUP), Beijing 100089, P. R. China

c Northwestern Polytechnical University, China, No. 127, Youyi West Road, Xi’an City, Shanxi Province, China

Abstract

This work presents the successful synthesis of a series of fused energetic compounds using the strategy of structural modification from local carbonyl to hydroxylamine, hydrazone or methylamine. Hydroxylamine-substituted compound 2 exhibits high density, high detonation performance and low sensitivities as a secondary explosive.

Graphical abstract: Synthesis of fused energetic compounds using structural modification from local carbonyl to hydroxylamine/hydrazone

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Article information

DOI
https://doi.org/10.1039/D3CC03330A
Article type
Communication
Submitted
11 Jul 2023
Accepted
25 Aug 2023
First published
25 Aug 2023

Chem. Commun., 2023,59, 11389-11392

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Synthesis of fused energetic compounds using structural modification from local carbonyl to hydroxylamine/hydrazone

C. Lei, C. Xiao, J. Tang, H. Yang, Q. Zhang and G. Cheng, Chem. Commun., 2023, 59, 11389 DOI: 10.1039/D3CC03330A

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