Issue 62, 2023
From the journal:

Chemical Communications

Selective synthesis of boron-substituted enynes via a one-pot diboration/protodeboration sequence†

Jakub Szyling, ORCID logo *a   Aleksandra Szymańskaab  and  Jędrzej Walkowiak ORCID logo *a  

* Corresponding authors

a Centre for Advanced Technology, Adam Mickiewicz University, Uniwersytetu Poznańskiego 10, 61-614 Poznan, Poland
E-mail: j.szyling@amu.edu.pl, jedrzej.walkowiak@amu.edu.pl

b Faculty of Chemistry, Adam Mickiewicz University, Uniwersytetu Poznańskiego 8, 61-614 Poznan, Poland

Abstract

An efficient and facile one-pot protocol to access enynylboronates via a Pt-catalyzed diboration/protodeboration strategy has been developed. The reaction is suitable for various silylsubstituted symmetrical and unsymmetrical 1,3-diynes, leading to π-conjugated organoboron compounds with excellent regio- and stereoselectivity.

Graphical abstract: Selective synthesis of boron-substituted enynes via a one-pot diboration/protodeboration sequence

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Article information

DOI
https://doi.org/10.1039/D3CC02695G
Article type
Communication
Submitted
05 Jun 2023
Accepted
26 Jun 2023
First published
17 Jul 2023
This article is Open Access
Creative Commons BY license

Chem. Commun., 2023,59, 9541-9544

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Selective synthesis of boron-substituted enynes via a one-pot diboration/protodeboration sequence

J. Szyling, A. Szymańska and J. Walkowiak, Chem. Commun., 2023, 59, 9541 DOI: 10.1039/D3CC02695G

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