Issue 58, 2023

Copper-mediated bromine atom transfer radical cyclisation of unactivated alkyl bromides

Abstract

The atom transfer radical cyclisation of unactivated alkyl bromides was realized by using a catalytic system of CuBr and Me6-TREN. This protocol is applicable to the preparation of five-membered rings from unsaturated primary and secondary bromides.

Graphical abstract: Copper-mediated bromine atom transfer radical cyclisation of unactivated alkyl bromides

Supplementary files

Article information

Article type
Communication
Submitted
18 May 2023
Accepted
26 Jun 2023
First published
27 Jun 2023

Chem. Commun., 2023,59, 8993-8996

Copper-mediated bromine atom transfer radical cyclisation of unactivated alkyl bromides

X. Yang, J. Zhou, S. Wu and W. Yu, Chem. Commun., 2023, 59, 8993 DOI: 10.1039/D3CC02430J

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