Issue 56, 2023

Improving the performance of β-diketonate-based DyIII single-molecule magnets displaying luminescence thermometry

Abstract

Herein, we present a luminescent single-molecule magnet, [Dy(acac)3bpm] (acac = acetylacetonate, bpm = 2,2′-bipyrimidine), which displays luminescence thermometry with a maximum thermal sensitivity of 1.5% K−1 (70 K) and effective energy barriers (309 K, 0 Oe; 345 K, 1200 Oe) among the largest reported for SMMs with thermometric capabilities.

Graphical abstract: Improving the performance of β-diketonate-based DyIII single-molecule magnets displaying luminescence thermometry

Supplementary files

Article information

Article type
Communication
Submitted
02 May 2023
Accepted
16 Jun 2023
First published
16 Jun 2023

Chem. Commun., 2023,59, 8723-8726

Improving the performance of β-diketonate-based DyIII single-molecule magnets displaying luminescence thermometry

A. G. Bispo-Jr, L. Yeh, D. Errulat, D. A. Gálico, F. A. Sigoli and M. Murugesu, Chem. Commun., 2023, 59, 8723 DOI: 10.1039/D3CC02148C

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