A synthetic cycle for iminophosphorane synthesis involving direct intermolecular NP bond formation on N2-derived molybdenum nitride

Li Jin; Guoqiang Zhang; Xiaoqin Yang; Jinyi Song; Jin Wang; Qian Liao

doi:10.1039/D3CC01925J

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A synthetic cycle for iminophosphorane synthesis involving direct intermolecular NP bond formation on N₂-derived molybdenum nitride†

Li Jin,^a Guoqiang Zhang,^a Xiaoqin Yang,^b Jinyi Song,^a Jin Wang

*^b and Qian Liao

*^a

Author affiliations

* Corresponding authors

^a Zhang Dayu School of Chemistry, Dalian University of Technology, No. 2 Linggong Rd, 116024 Dalian, Liaoning, China
E-mail: liaoq@dlut.edu.cn

^b School of Pharmacy, Jiangsu Province Engineering Research Center of Tumor Targeted Nano Diagnostic and Therapeutic Materials, Yancheng Teachers University, Yancheng, Jiangsu, China
E-mail: wangj01@yctu.edu.cn

Abstract

N [double bond, length as m-dash] P bonds were built straightforwardly between N₂-derived molybdenum terminal nitride and phosphines. Subsequent PCET, oxidative decarbonylation and then reduction regenerated the N₂ complex, developing a synthetic cycle transferring N₂ into various iminophosphoranes. Both aryl and alkyl substituted phosphines proceeded smoothly.

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Article information

DOI: https://doi.org/10.1039/D3CC01925J
Article type: Communication
Submitted: 19 Apr 2023
Accepted: 30 May 2023
First published: 31 May 2023

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Chem. Commun., 2023,59, 7955-7958

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A synthetic cycle for iminophosphorane synthesis involving direct intermolecular NP bond formation on N₂-derived molybdenum nitride

L. Jin, G. Zhang, X. Yang, J. Song, J. Wang and Q. Liao, Chem. Commun., 2023, 59, 7955 DOI: 10.1039/D3CC01925J

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Chemical Communications