Statically and dynamically flexible hydrogen-bonded frameworks based on 4,5,9,10-tetrakis(4-carboxyphenyl)pyrene

Taito Hashimoto; Ryusei Oketani; Asato Inoue; Kohei Okubo; Kouki Oka; Norimitsu Tohnai; Kazuhide Kamiya; Shuji Nakanishi; Ichiro Hisaki

doi:10.1039/D3CC01877F

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Statically and dynamically flexible hydrogen-bonded frameworks based on 4,5,9,10-tetrakis(4-carboxyphenyl)pyrene†

Taito Hashimoto,^a Ryusei Oketani,

^ab Asato Inoue,^a Kohei Okubo,^c Kouki Oka,

^cd Norimitsu Tohnai,

^c Kazuhide Kamiya,

^ab Shuji Nakanishi

^ab and Ichiro Hisaki

*^ab

Author affiliations

* Corresponding authors

^a Division of Chemistry, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan
E-mail: i.hisaki.es@osaka-u.ac.jp

^b Research Center for Solar Energy Chemistry, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan

^c Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan

^d Center for Future Innovation (CFi), Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan

Abstract

Aperture shape and size of flexible hydrogen-bonded organic frameworks (HOF) were statically modulated using various aromatic solvents, and dynamically changed by desorption and adsorption of the solvent molecules.

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DOI: https://doi.org/10.1039/D3CC01877F
Article type: Communication
Submitted: 17 Apr 2023
Accepted: 18 May 2023
First published: 18 May 2023
This article is Open Access

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Chem. Commun., 2023,59, 7224-7227

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Statically and dynamically flexible hydrogen-bonded frameworks based on 4,5,9,10-tetrakis(4-carboxyphenyl)pyrene

T. Hashimoto, R. Oketani, A. Inoue, K. Okubo, K. Oka, N. Tohnai, K. Kamiya, S. Nakanishi and I. Hisaki, Chem. Commun., 2023, 59, 7224 DOI: 10.1039/D3CC01877F

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Chemical Communications

Statically and dynamically flexible hydrogen-bonded frameworks based on 4,5,9,10-tetrakis(4-carboxyphenyl)pyrene†

Abstract

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Statically and dynamically flexible hydrogen-bonded frameworks based on 4,5,9,10-tetrakis(4-carboxyphenyl)pyrene

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