Trans-1,2-di(1-pyrenylamino)cycloxexane was found to display circularly polarized excimer emission (glum = 0.016) both in polar and non-polar solvents that is assigned to charge separation symmetry breaking on the basis of its large transition state dipole moment (12.1 D).
M. J. Álvaro-Martins, C. Billiaux, P. Godard, R. Oda, G. Raffy and D. M. Bassani, Chem. Commun., 2023, 59, 7963 DOI: 10.1039/D3CC01802D
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