Issue 45, 2023
From the journal:

Chemical Communications

Zn-ProPhenol catalyzed asymmetric inverse-electron-demand Diels–Alder reaction†

Yu-Hang Miao,a   Yuan-Zhao Hua,*a   Shi-Kun Jia,a   Xiao Xiao, ORCID logo b   Min-Can Wang ORCID logo *a  and  Guang-Jian Mei ORCID logo *a  

* Corresponding authors

a Green Catalysis Center, and College of Chemistry, Zhengzhou University, Zhengzhou 450001, China
E-mail: hyzh@gs.zzu.edu.cn, wangmincan@zzu.edu.cn, meigj@zzu.edu.cn

b Institute of Pharmaceutical Science and Technology, Zhejiang University of Technology, Hangzhou 310014, People's Republic of China

Abstract

The first Zn-ProPhenol catalyzed asymmetric inverse-electron-demand Diels–Alder reaction has been accomplished. This protocol was carried out by a dual-activation mode under mild conditions, allowing the preparation of various biologically important dihydropyrans in good yields with excellent stereoselectivities.

Graphical abstract: Zn-ProPhenol catalyzed asymmetric inverse-electron-demand Diels–Alder reaction

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Article information

DOI
https://doi.org/10.1039/D3CC01641B
Article type
Communication
Submitted
04 Apr 2023
Accepted
15 May 2023
First published
16 May 2023

Chem. Commun., 2023,59, 6929-6932

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Zn-ProPhenol catalyzed asymmetric inverse-electron-demand Diels–Alder reaction

Y. Miao, Y. Hua, S. Jia, X. Xiao, M. Wang and G. Mei, Chem. Commun., 2023, 59, 6929 DOI: 10.1039/D3CC01641B

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