Issue 35, 2023

Coinage metal complexes of multidentate Pacman phosphane ligands

Abstract

We present the extension of Pacman ligands to bidentate phosphane ligands enabling them to bind metals in their sterically protected cavity. The coordination of coinage metals shows the ability of the ligand to adopt different coordination modes by distortion, of which some additionally include the imine nitrogen atoms. Besides the coordinated metal, the substitution on the phosphorus atoms influences the type of coordination.

Graphical abstract: Coinage metal complexes of multidentate Pacman phosphane ligands

Supplementary files

Article information

Article type
Communication
Submitted
09 Mar 2023
Accepted
30 Mar 2023
First published
03 Apr 2023

Chem. Commun., 2023,59, 5245-5248

Coinage metal complexes of multidentate Pacman phosphane ligands

L. Ohms, L. Eickhoff, P. Kramer, A. Villinger, J. Bresien and A. Schulz, Chem. Commun., 2023, 59, 5245 DOI: 10.1039/D3CC01174G

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