A photochromic metallacycle with highly anisotropic Dy–F magnetic units

Nour El Beyrouti; Felix Houard; Marie Cordier; Elzbieta Trzop; Stéphane Rigaut; Boris Le Guennic; Kevin Bernot; Lucie Norel

doi:10.1039/D3CC01037F

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A photochromic metallacycle with highly anisotropic Dy–F magnetic units†

Nour El Beyrouti,^a Felix Houard,

^a Marie Cordier,^a Elzbieta Trzop,

^b Stéphane Rigaut,

^a Boris Le Guennic,

^a Kevin Bernot

^a and Lucie Norel

*^a

Author affiliations

* Corresponding authors

^a Univ Rennes, INSA Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes) – UMR 6226, F-35000 Rennes, France
E-mail: lucie.norel@univ-rennes1.fr

^b Univ Rennes, CNRS, IPR (Institut de Physique de Rennes) – UMR 6251, F-35000 Rennes, France

Abstract

A dinuclear metallacycle assembled from a bispyridyl dithienylethene linker and a highly anisotropic dysprosium based Single Molecule Magnet (SMM) shows magnetic hysteresis at 1.8 K together with photoisomerization in single crystals (SC). The impact of photoswitching on the SMM behavior is evidenced and related to the specific organization of the magnetic units.

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DOI: https://doi.org/10.1039/D3CC01037F
Article type: Communication
Submitted: 01 Mar 2023
Accepted: 18 Mar 2023
First published: 22 Mar 2023
This article is Open Access

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Chem. Commun., 2023,59, 5265-5268

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A photochromic metallacycle with highly anisotropic Dy–F magnetic units

N. El Beyrouti, F. Houard, M. Cordier, E. Trzop, S. Rigaut, B. Le Guennic, K. Bernot and L. Norel, Chem. Commun., 2023, 59, 5265 DOI: 10.1039/D3CC01037F

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Chemical Communications

A photochromic metallacycle with highly anisotropic Dy–F magnetic units†

Abstract

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A photochromic metallacycle with highly anisotropic Dy–F magnetic units

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