Issue 29, 2023

Elimination of grain boundary resistance in vanadoborate electrolyte via the hydrogen-bond interaction of glycerol

Abstract

An effective method to eliminate grain boundary resistance of crystalline vanadoborate electrolyte was developed. This method involved the addition of glycerol to result in the formation of many hydrogen bonds between crystal grains, facilitating a rapid transfer of protons across grain boundaries. Using this method, the intrinsic conduction of vanadoborate electrolyte was fully reflected in its bulk materials, valuable for advancing our understanding of vanadoborate electrolytes and for promoting the application of these electrolytes.

Graphical abstract: Elimination of grain boundary resistance in vanadoborate electrolyte via the hydrogen-bond interaction of glycerol

Supplementary files

Article information

Article type
Communication
Submitted
29 Jan 2023
Accepted
09 Mar 2023
First published
13 Mar 2023

Chem. Commun., 2023,59, 4312-4315

Elimination of grain boundary resistance in vanadoborate electrolyte via the hydrogen-bond interaction of glycerol

S. Zhang, Y. Lu, X. Sun, H. Tian, X. Bai and S. Liu, Chem. Commun., 2023, 59, 4312 DOI: 10.1039/D3CC00404J

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