Issue 25, 2023
From the journal:

Chemical Communications

Reactivity of vinylidene-π-allyl palladium(ii) species†

Can Li,ab   Zhengnan Zhou,ab   Yuling Li,ab   Yinlong Guo ORCID logo *ab  and  Shengming Ma ORCID logo *ac  

* Corresponding authors

a State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, P. R. China
E-mail: ylguo@mail.sioc.ac.cn, masm@sioc.ac.cn

b University of Chinese Academy of Sciences, Beijing 100049, P. R. China

c Research Center for Molecular Recognition and Synthesis, Department of Chemistry, Fudan University, 220 Handan Lu, Shanghai 200433, P. R. China

Abstract

The reactivity of a new type of organometallic intermediate, vinylidene-π-allyl palladium species, has been demonstrated: the reaction between 4-alken-2-ynyl carbonates and stabilized carbon nucleophiles afforded functionalized 1,2,3,-butatriene compounds in moderate to high yields and excellent regioselectivities.

Graphical abstract: Reactivity of vinylidene-π-allyl palladium(ii) species

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Article information

DOI
https://doi.org/10.1039/D2CC06871K
Article type
Communication
Submitted
17 Dec 2022
Accepted
21 Feb 2023
First published
25 Feb 2023
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2023,59, 3727-3730

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Reactivity of vinylidene-π-allyl palladium(II) species

C. Li, Z. Zhou, Y. Li, Y. Guo and S. Ma, Chem. Commun., 2023, 59, 3727 DOI: 10.1039/D2CC06871K

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