Issue 1, 2023

Selectfluor®-enabled photochemical selective C(sp3)–H(sulfonyl)amidation

Abstract

Transition metal- and photosensitizer-free C(sp3)–H (sulfonyl)amidation reactions have been realized by employing Selectfluor® as a versatile reagent, functioning as a photoactive component, a HAT precursor and an oxidant. Various toluene derivatives, cycloalkanes, natural products and bioactive molecules can be converted into N-containing products under mild conditions in good yield and with high chemo- and site-selectivity.

Graphical abstract: Selectfluor®-enabled photochemical selective C(sp3)–H(sulfonyl)amidation

Supplementary files

Article information

Article type
Communication
Submitted
13 Oct 2022
Accepted
28 Nov 2022
First published
29 Nov 2022

Chem. Commun., 2023,59, 118-121

Selectfluor®-enabled photochemical selective C(sp3)–H(sulfonyl)amidation

Y. Chen, B. Yang, Q. Li, Y. Lin and L. Gong, Chem. Commun., 2023, 59, 118 DOI: 10.1039/D2CC05569D

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