The green synthesis of magnesium oxide nanocomposite-based solid phase for the extraction of arsenic, cadmium, and lead from drinking water

Abstract

Solid-phase extraction (SPE) has attracted the attention of scientists because it can increase the selectivity and sensitivity measurements of analytes. Therefore, this study is designed to synthesise magnesium oxide nanoparticles (D-MgO-NPs) by an eco-friendly method using biogenic sources Duranta erecta followed by fabricating its chitosan-based polymeric composite (D-MgO-NC) for the SPE of heavy metals (HMs), i.e., arsenic (As), cadmium (Cd), and lead (Pb) from drinking water. Various analytical techniques were used for the surface characterization of D-MgO-NPs and D-MgO-NC. FTIR findings confirmed the formation of D-MgO-NC based on MgO association with the –OH/–NH₂ of the chitosan. D-MgO-NC showed the smallest size of particles with rough surface morphology, followed by the crystalline cubic structure of MgO in its nanoparticle and composites. The synthesised D-MgO-NC was used as an adsorbent for the SPE of HMs from contaminated water, followed by their detection by atomic absorption spectrometry. Various experimental parameters, including pH, flow rate, the concentration of HMs, eluent composition, and volume, were optimised for the preconcentration of HMs. The limits of detection for As, Cd, and Pb of the proposed D-MgO-NC-based SPE method were found to be 0.008, 0.006, and 0.012 μm L⁻¹, respectively. The proposed method has an enrichment factor and relative standard deviation of >200 and <5.0%, respectively. The synthesised D-MgO-NC-based SPE method was successfully applied for the quantitative detection of As, Cd, and Pb in groundwater samples, which were found in the range of 18.3 to 15.2, 3.20 to 2.49, and 8.20 to 6.40 μg L⁻¹, respectively.