Issue 16, 2022

Pore and grain chemistry during sintering of garnet-type Li6.4La3Zr1.4Ta0.6O12 solid-state electrolytes

Abstract

Garnet-type solid-state electrolytes have significant advantages over liquid organic electrolytes but require energy-intensive sintering to achieve high density and ionic conductivity. The aim of this study is to understand the chemical and microstructural evolution towards optimizing sintering conditions to achieve good conductivity at low sintering temperatures. To this end, the pore surface chemistry, morphology, and elemental enrichment along grain boundaries are investigated using scanning electron microscopy, X-ray scattering, and thermo-gravimetric analysis at temperatures below and above 1000 °C where the conductivity is significantly affected. Combined with theoretical simulations, three transition regions during the temperature ramp to 900 °C were identified: (1) 200 °C to 350 °C where the air-exposed protonated Li6.4La3Zr1.4Ta0.6O12 (H-LLZTO) releases H+ and the lattice constant decreases, (2) 550 °C to 700 °C where the LLZTO surface structure becomes unstable, which leads to the formation of a La2Zr2O7 (LZO) phase, and (3) 700 °C to 870 °C, where the surface Li2CO3 layer starts to decompose and react with the intermediate LZO phase to reform the LLZTO cubic phase. While gradual densification is observed between 750 °C and 900 °C, higher temperatures (1000 °C and above) significantly reduce the pore volume and increase the conductivity. Backscattered electron (BSE) imaging and energy dispersive spectroscopy (EDS) under cryo conditions reveals Ta enrichment and Zr depletion at grain boundaries after sintering at 1100 °C for 6 hours.

Graphical abstract: Pore and grain chemistry during sintering of garnet-type Li6.4La3Zr1.4Ta0.6O12 solid-state electrolytes

Supplementary files

Article information

Article type
Paper
Submitted
02 Dec 2021
Accepted
10 Mar 2022
First published
11 Mar 2022
This article is Open Access
Creative Commons BY license

J. Mater. Chem. A, 2022,10, 9080-9090

Pore and grain chemistry during sintering of garnet-type Li6.4La3Zr1.4Ta0.6O12 solid-state electrolytes

J. A. Hammons, J. A. Espitia, E. Ramos, R. Shi, F. Meisenkothen, M. Wood, M. R. Cerón and J. Ye, J. Mater. Chem. A, 2022, 10, 9080 DOI: 10.1039/D1TA10338E

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