Activated carbon prepared by co-pyrolysis of waste tobacco straw and waste LDPE mulch film: characterization and application for methylene blue removal

Abstract

Efficient and inexpensive sorbents play a key role in removing organic pollutants from water bodies. In this study, a series of high surface area activated carbons (ACs) with excellent adsorption performance was prepared by co-pyrolysis of the waste tobacco straw and the waste low-density polyethylene (LDPE) mulch film. Using the maximum adsorption capacity of methylene blue (MB) as an indicator, the variables such as LDPE content, K₂CO₃ to raw material ratio, activation time, and activation temperature were optimized. The optimal synthesis conditions were as follows: LDPE content of 40%, K₂CO₃/raw material ratio of 1 : 2, activation temperature of 900 °C, and activation time of 100 min. The maximum adsorption capacity of MB was up to 849.91 mg g⁻¹. The results of scanning electron microscopy (SEM), X-ray powder diffraction (XRD), Raman, X-ray photoelectron spectroscopy (XPS), and BET showed that the moderate addition of LDPE was beneficial to the pyrolysis of the waste tobacco straw, bringing about the enrichment of surface groups (–OH, –COOH) and increasing its specific surface area and pore volume (up to 1566.7 m² g⁻¹ and 0.996 cm³ g⁻¹, respectively). The equilibrium data of MB adsorption by the composite activated carbon (PAC) was consistent with the Langmuir isotherm, while the adsorption kinetics were better described by a pseudo-second-order kinetic model. This work reveals the feasibility of LDPE mulch film and waste tobacco straw as potential and inexpensive precursors for preparing high surface area AC adsorbents.