Durability and corrosion behaviors of superhydrophobic amorphous coatings: a contrastive investigation

Abstract

Superhydrophobic surfaces can be derived from roughening hydrophobic materials. However, the superhydrophobic surfaces with various micro/nano morphologies present variations of chemical and mechanical durability, which limits their practical applications. Very little actually is known about comparing durability and corrosion resistance of concave and convex superhydrophobic surface structures systematically. In this paper, two kinds of superhydrophobic AlNiTi amorphous coatings with concave and convex surfaces were obtained by chemical etching and hydrothermal methods, respectively. Benefiting from nanoscale sheet structure, the convex superhydrophobic coating displays higher water-repellence (contact angle = 157.6°), better self-cleaning performance and corrosion resistance. The corrosion current density of the convex superhydrophobic surface is approximately one order of magnitude smaller than the concave superhydrophobic surface. Besides, the long-term chemical stability and mechanical durability of both superhydrophobic surfaces were also investigated. The formation and damage mechanisms of these two kinds of superhydrophobic surfaces were proposed. It is hoped that these investigations could provide clear guidance for the real-world applications of superhydrophobic amorphous coatings.