Degradation of sulfadiazine in aqueous media by peroxymonosulfate activated with biochar-supported ZnFe2O4 in combination with visible light in an internal loop-lift reactor

Abstract

Solid waste resource utilization and the treatment of wastewater are two important aspects in environmental protection. Here, biochar (BC) derived from municipal sewage sludge has been combined with ZnFe₂O₄ to form the photocatalyst ZnFe₂O₄/biochar (ZnFe/BC), and it was used to degrade sulfadiazine (SDZ) in the presence of peroxymonosulfate (PMS) under visible (Vis) light irradiation in an internal loop-airlift reactor (ALR). The surface morphology and structure of ZnFe/BC have been characterized by X-ray diffraction (XRD), scanning electron microscopy equipped with an attachment for energy-dispersive spectroscopy (SEM-EDS), X-ray photoelectron spectroscopy (XPS), and UV-Vis diffuse reflectance spectroscopy (UV-Vis DRS). ZnFe/BC displays outstanding photocatalytic performance and reusability. After four reuse cycles of ZnFe/BC in the Vis/ZnFe/BC/PMS system, the SDZ degradation rate and efficiency still reached 0.082 min⁻¹ and 99.05%, respectively. Reactive species in this system included free radicals SO₄˙⁻, ˙OH, and ˙O₂⁻, as well as non-radicals ¹O₂, e⁻, and h⁺, as established from the results of chemical quenching experiments and electron paramagnetic resonance (EPR) analyses. Moreover, a mechanism of action of the Vis/ZnFe/BC/PMS system for SDZ degradation was proposed. The acute toxicity of the reaction solution towards Photobacterium phosphoreum T3 spp. in the Vis/ZnFe/BC/PMS process increased during the first 40 min and then decreased, illustrating that Vis/ZnFe/BC/PMS provided an effective and safe method for the removal of SDZ.