Issue 33, 2022, Issue in Progress
From the journal:

RSC Advances

Ring-opening of non-activated aziridines with [11C]CO2via novel ionic liquids†

Anton Lindberg*a  and  Neil Vasdev ORCID logo *ab  

* Corresponding authors

a Azrieli Centre for Neuro-Radiochemistry, Brain Health Imaging Centre, Centre for Addiction and Mental Health, Toronto, ON, Canada
E-mail: anton.lindberg@camh.ca

b Department of Psychiatry, University of Toronto, Toronto, ON, Canada
E-mail: neil.vasdev@utoronto.ca

Abstract

Novel ionic liquids based on DBU and DBN halide salts were developed as a catalytic system for ring-opening of non-activated aziridines with [11C]CO2. The ability of ionic liquids to activate aziridines represents a simple methodology for the synthesis of 11C-carbamates and can be extended for CO2-fixation in organic and radiochemistry.

Graphical abstract: Ring-opening of non-activated aziridines with [11C]CO2 via novel ionic liquids

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Article information

DOI
https://doi.org/10.1039/D2RA03966D
Article type
Paper
Submitted
27 Jun 2022
Accepted
14 Jul 2022
First published
02 Aug 2022
This article is Open Access
Creative Commons BY license

RSC Adv., 2022,12, 21417-21421

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Ring-opening of non-activated aziridines with [11C]CO2 via novel ionic liquids

A. Lindberg and N. Vasdev, RSC Adv., 2022, 12, 21417 DOI: 10.1039/D2RA03966D

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