Wild jujube-based fluorescent carbon dots for highly sensitive determination of oxalic acid

Abstract

Fluorescent carbon dots (CDs) were synthesized by a one-step hydrothermal treatment of wild jujube and DL-tryptophan. The structure and properties of the CDs were confirmed by transmission electron microscopy, X-ray photoelectron spectroscopy, ultraviolet visible absorption spectroscopy, fluorescence spectroscopy and so on. The as-prepared CDs exhibit excellent excitation-independent but pH-dependent (4.0–12.0) fluorescent features and emit blue strong fluorescence under 365 nm light. Hg²⁺ can decrease the fluorescence intensity of the CDs through static quenching, while the addition of oxalic acid (OA) recovers it owing to the coordination binding between oxalic acid and Hg²⁺. Based on this, the as-prepared CDs were used as a new “off–on” fluorescent probe for highly sensitive determination of oxalic acid with a wide linear detection range of 0.1–20 mg L⁻¹ and a low detection limit of 0.057 mg L⁻¹. Moreover, the fluorescent probe was successfully applied to detect oxalic acid in tomato and cherry tomato samples with satisfactory results.