3-(4-Formylphenyl)-triazole functionalized coumarins as violet-blue luminophores and n-type semiconductors: synthesis, photophysical, electrochemical and thermal properties

Abstract

3-(4-Formylphenyl)-triazole-coumarin hybrid chromophores (FPhTCs) were synthesized in good yields, using a click chemistry protocol, and were also structurally characterized. Their photophysical, electrochemical and thermal properties were measured demonstrating that FPhTCs are luminescent in the blue-violet region of the electromagnetic spectrum, both in solution and the solid state. They showed an electrochemical band-gap values of 2.79 ± 0.08 eV, resistivity values between 10⁴ and 10⁵ Ω cm and are thermally stable up to 225 °C, properties that promise FPhTCs as good candidates for optoelectronic or imaging applications. Their solution and solid state photoluminescent properties are discussed and supported by theoretical calculations.