A Eu(iii) metal–organic framework based on anthracenyl and alkynyl conjugation as a fluorescence probe for the selective monitoring of Fe3+ and TNP

Abstract

In this work, a luminescent metal–organic framework (Eu-MOF {[Eu₆L₆(μ₃-OH)₈(H₂O)₃]₈·H₂O}_n) was constructed by a solvothermal method with a linear organic ligand L (10-[(2-amino-4-carboxyl-phenyl)ethynyl]anthracene-9-carboxylic acid) based on anthracene and alkyne groups and using Eu³⁺ as the metal center. The MOF exhibits a stable UiO-66 crystal structure, and a six-core cluster twelve-linked secondary structural unit was successfully synthesized using 2-fluorobenzoic acid as a modulator, forming a classical fcu topology. Moreover, it exhibits good chemical stability. Interestingly, Eu-MOF exhibited high selectivity and sensitive fluorescence burst properties towards Fe³⁺ ions and 2,4,6-trinitrophenol (TNP) in DMF solution. For Fe³⁺, the K_SV value is 5.06 × 10⁵ M⁻¹ and the LOD value is 5.1 × 10⁻⁷ M. For TNP, the K_SV value is 1.92 × 10⁴ M⁻¹ and the LOD value is 1.93 × 10⁻⁶ M. In addition, Eu-MOF showed good anti-interference ability and fast response. This work provides an excellent fluorescent sensor for the detection of Fe³⁺ and 2,4,6-trinitrophenol (TNP) residues in contaminants.