Effects of diluent gases on sooting transition process in ethylene counterflow diffusion flames

Abstract

The impacts of adding diluent gases (nitrogen, carbon dioxide, and helium) either to the fuel side or the oxidizer side on the sooting transition process in ethylene counterflow diffusion flames are investigated experimentally and numerically. A series of ethylene flames ranging from non-sooting to heavy-sooting are studied by gradually increasing the oxygen concentration on the oxidizer side. The optical method is used to analyze flame images, determining the sooting transition process. It is found that whether CO₂ is added to the fuel side or the oxidizer side, the sooting transition process is delayed significantly. This process is slightly delayed when He is added to the fuel side, however, it is promoted when He is introduced to the oxidizer side. The numerical results show that in CO₂-diluted flames, the mole fraction of the main soot precursors C₂H₂, C₃H₃, and C₆H₆ are reduced, which leads to the delay of soot formation. In addition, the H radical decreases while the OH radical increases, both of them are important for soot formation. In He-diluted flames, the concentration of C₂H₂, C₃H₃, and C₆H₆ decreased, as well as H and OH radicals. Moreover, adding He obviously changes the distribution area of products.