Issue 26, 2022

N,N-Dimethylformamide-stabilized ruthenium nanoparticle catalyst for β-alkylated dimer alcohol formation via Guerbet reaction of primary alcohols

Abstract

N,N-Dimethylformamide-stabilized Ru nanoparticles (NPs) provide a highly efficient catalyst for the Guerbet reaction of primary alcohols. DMF-modified Ru NPs were synthesized, and characterized by transition electron microscopy, and X-ray absorption spectroscopy, X-ray photoelectronspectroscopy, and Fourier-transform infrared spectroscopy. The Ru NP catalyst was highly durable during catalytic reactions under external additive/solvent-free conditions.

Graphical abstract: N,N-Dimethylformamide-stabilized ruthenium nanoparticle catalyst for β-alkylated dimer alcohol formation via Guerbet reaction of primary alcohols

Supplementary files

Article information

Article type
Paper
Submitted
13 Apr 2022
Accepted
26 May 2022
First published
06 Jun 2022
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2022,12, 16599-16603

N,N-Dimethylformamide-stabilized ruthenium nanoparticle catalyst for β-alkylated dimer alcohol formation via Guerbet reaction of primary alcohols

T. Nagata, K. Okada, R. Kondo, T. Toyao, K. Shimizu, T. Suzuki and Y. Obora, RSC Adv., 2022, 12, 16599 DOI: 10.1039/D2RA02381D

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