Prospective application of phosphorylated carbon nanofibers with a high adsorption capacity for the sequestration of uranium from ground water

Abstract

In this study carbon nanofibers (CNF) were phosphorylated by using ortho-phosphoric acid and applied for adsorptive remediation of uranium from water. The phosphorylated carbon nanofibers (PCNF) showed 96% removal of uranium as compared to 79% by CNF. The adsorption data from batch adsorption studies fitted well with the Langmuir model and a maximum adsorption capacity of 512.8 mg g⁻¹ was obtained at pH 6.0 while the adsorption followed pseudo second order kinetics. A detailed characterisation of the adsorbent has been carried out using various analytical and spectroscopic tools. The application of the adsorbent to ground water samples exhibited promising results even in the presence of other interfering cations and anions which is imperative considering the toxic effects of uranium in ground water.