Reactions of [60]fullerene with alkynes promoted by OH−

Wei-Wei Chang; Fa-Hui He; Alberto García-Peñas; Mehdihasan I. Shekh; Zong-Jun Li

doi:10.1039/D2RA01300B

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Reactions of [60]fullerene with alkynes promoted by OH⁻†

Wei-Wei Chang,

^ab Fa-Hui He,

*^bc Alberto García-Peñas,

^d Mehdihasan I. Shekh

^e and Zong-Jun Li^b

Author affiliations

* Corresponding authors

^a Analysis & Testing Center, Shandong University of Technology, Zibo 255049, China

^b State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Changchun 130022, China

^c State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
E-mail: hefg@dicp.ac.cn

^d Department of Materials Science and Engineering and Chemical Engineering, IAAB, University Carlos III of Madrid, Madrid 28911, Spain

^e New Energy Materials Laboratory, College of Materials Science, Shenzhen University, Shenzhen 518055, China

Abstract

In the current work, the reactions of [60]fullerene with alkynes promoted by OH⁻ (base) are addressed. The treatment of C₆₀ with alkynes in the presence of TBAOH produces alkynylation products (R-C₆₀–H) with high selectivity in o-DCB at 100 °C. Plausible reaction mechanisms were proposed. This work provides a convenient and environmental friendly method for the functionalization of fullerenes.

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Correction: Reactions of [60]fullerene with alkynes promoted by OH−

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Article information

DOI: https://doi.org/10.1039/D2RA01300B
Article type: Paper
Submitted: 26 Feb 2022
Accepted: 28 Apr 2022
First published: 10 May 2022
This article is Open Access

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RSC Adv., 2022,12, 14018-14021

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Reactions of [60]fullerene with alkynes promoted by OH⁻

W. Chang, F. He, A. García-Peñas, M. I. Shekh and Z. Li, RSC Adv., 2022, 12, 14018 DOI: 10.1039/D2RA01300B

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