SCHEDULED MAINTENANCE
Planar chiral [2.2]paracyclophanes are resolved through the direct C–H arylation of enantiopure oxazolines, providing a convenient route to ligands and chiral materials. Preliminary results show that hydrolysis followed by decarboxylative phosphorylation leads to enantiopure [2.2]paracyclophane derivatives that are otherwise challenging to prepare.
![Graphical abstract: The concise synthesis and resolution of planar chiral [2.2]paracyclophane oxazolines by C–H activation](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=D2RA01075E&imageInfo.ImageIdentifier.Year=2022)
S. Tewari, M. N. Mungalpara, S. Patel and G. J. Rowlands, RSC Adv., 2022, 12, 8588 DOI: 10.1039/D2RA01075E
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