Optimized nano-metal particles filled into carbon nanohorns to achieve high N-doping amount and high porosity for enhanced oxygen evolution reaction

Abstract

Nano-metal-filled N-doped carbon materials have been actively verified as promising alternatives for precious-metal catalysts in the oxygen evolution reaction (OER). Herein, Ni/Fe/Cu-filled N-doped carbon nanohorns (CNHs) are synthesized via a positive pressure assisted arc discharge method using a Ni/Fe/Cu rod charged in an anode hole in a N₂ and Ar mixture. We first found that the amount of N atom doping can be controlled by the types of nano-metal particles encapsulated by CNHs. The content of N atoms on CNHs uniquely depended on the initial Ni wires inserted into the anode graphite; increasing the number of Ni wires induced the enrichment of N atoms until 3.56 at%, whereas the content of N atoms for Cu- and Fe-filled CNHs is against the results; loading Cu and Fe nanoparticles decreases the N-doping amount. And the morphologies and N-configurations can be changed by the types of metal nanoparticles. Furthermore, the OER performance of Ni-filled CNHs is much superior to that of Cu- and Fe-filled CNHs, which can be significantly enhanced by the tip opening structure, and the increase in Ni loading amount and the N atom content.