Rational and site-selective formation of coordination polymers consisting of d10 coinage metal ions with thiolate ligands using a metal ion-doped polymer substrate

Takaaki Tsuruoka; Yuri Miyashita; Ryuki Yoshino; Myu Fukuoka; Shoya Hirao; Yohei Takashima; Aude Demessence; Kensuke Akamatsu

doi:10.1039/D2RA00269H

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Rational and site-selective formation of coordination polymers consisting of d¹⁰ coinage metal ions with thiolate ligands using a metal ion-doped polymer substrate†

Takaaki Tsuruoka,

*^a Yuri Miyashita,^a Ryuki Yoshino,^a Myu Fukuoka,^a Shoya Hirao,^a Yohei Takashima,

^a Aude Demessence

^b and Kensuke Akamatsu^a

Author affiliations

* Corresponding authors

^a Department of Nanobiochemistry, Frontiers of Innovative Research in Science and Technology (FIRST), Konan University, 7-1-20 Minatojimaminami, Chuo-ku, Kobe 650-0047, Japan
E-mail: tsuruoka@konan-u.ac.jp

^b Univ Lyon, Université Claude Bernard Lyon 1, Institut de Recherches sur la Catalyse et l'Environnement de Lyon (IRCELYON), UMR 5256, CNRS, Villeurbanne, France

Abstract

Here, we report an interfacial approach for fabricating coordination polymers (CPs) consisting of d¹⁰ coinage metal ions with thiolate ligands on a polymer substrate. It was found that CPs were selectively formed on the polymer substrate, resulting in the formation of CP-based thin films. In addition, utilizing a mixed metal ion-doped polymer substrate leads to the formation of mixed-metal CP-based films.

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Article information

DOI: https://doi.org/10.1039/D2RA00269H
Article type: Paper
Submitted: 14 Jan 2022
Accepted: 20 Jan 2022
First published: 28 Jan 2022
This article is Open Access

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RSC Adv., 2022,12, 3716-3720

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Rational and site-selective formation of coordination polymers consisting of d¹⁰ coinage metal ions with thiolate ligands using a metal ion-doped polymer substrate

T. Tsuruoka, Y. Miyashita, R. Yoshino, M. Fukuoka, S. Hirao, Y. Takashima, A. Demessence and K. Akamatsu, RSC Adv., 2022, 12, 3716 DOI: 10.1039/D2RA00269H

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