Fabrication of a zinc oxide/alginate (ZnO/Alg) bionanocomposite for enhanced dye degradation and its optimization study

Abstract

This paper studies a new response surface methodology (RSM) based on the central composite design (CCD) modeling method to optimize the photocatalytic degradation of methylene blue (MB) and methyl orange (MO) by using a synthesized ZnO/Alg bionanocomposite under UV irradiation. ZnO with different content of sodium alginate (Alg) (10, 20, and 30% by weight) has been synthesized by a one-step sol–gel method. Zinc oxide (ZnO) nanoparticles were impregnated on the alginate polymer. Various characterization techniques were used to describe the physical and chemical properties of each catalyst such as XRD, FTIR, UV-vis, PL, FESEM, Raman, and BET. The optimal catalyst for MB and MO photocatalytic degradation process was discussed mathematically as a function of catalyst dose, irradiation time, and MB and MO concentration, which was modeled by CCD-RSM based on a statistical model (quadratic regression) and an optimization process (ANOVA analysis). The photocatalytic degradation efficiency of 98% was achieved for the optimal conditions of a dye concentration of 20 mg L⁻¹, the catalyst dose of 0.34 g L⁻¹, and an irradiation time of 90 min at pH 6. The measurement result (R² = 0.9901) showed that the considered model is very suitable, and the selected CCD-RSM successfully optimized the photodegradation conditions of MB and MO.