Issue 20, 2022
From the journal:

Organic Chemistry Frontiers

Charge transfer complex enabled photoreduction of Wittig phosphonium salts†

Fang Tan, ORCID logo ac   Peng Zheng,b   Qiang Liu*c  and  Xiang-Yu Chen ORCID logo *c  

* Corresponding authors

a School of Chemical Engineering, Guizhou Minzu University, Guiyang 550025, China

b Jinan Institute for Food and Drug Control, Jinan 250000, China

c School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China
E-mail: liuqiang@ucas.ac.cn, chenxiangyu20@ucas.ac.cn

Abstract

A photoinduced charge transfer complex strategy enabled (alkoxycarbonyl)methylation reaction of alkenes with phosphonium salts has been reported. This strategy provides a convenient strategy to functionalize indoles, 1,1-diphenylethylenes, enamides, and N-phenyl acrylamides with easily available phosphonium salts.

Graphical abstract: Charge transfer complex enabled photoreduction of Wittig phosphonium salts

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Article information

DOI
https://doi.org/10.1039/D2QO01079H
Article type
Research Article
Submitted
06 Jul 2022
Accepted
25 Aug 2022
First published
26 Aug 2022

Org. Chem. Front., 2022,9, 5469-5472

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Charge transfer complex enabled photoreduction of Wittig phosphonium salts

F. Tan, P. Zheng, Q. Liu and X. Chen, Org. Chem. Front., 2022, 9, 5469 DOI: 10.1039/D2QO01079H

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